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Platinum · SURFACE · CATALYSIS
More surface area for reactions
Chemistry also happens at edges and facets.
Pt
01 / WHAT CHANGES
The mechanism
In a catalyst, reactions occur at active sites on the surface. Reducing size can increase the proportion of accessible atoms, but those atoms are not all equivalent: facets, edges and interactions with the support influence reactivity.
02 / WHERE IT LEADS
An application, in context
One research example is the oxidation of 2-propanol on supported platinum nanoparticles. Differences in reactivity have been observed between particles with similar sizes but different shapes.
SOURCES FOR FURTHER READING
Ahmadi et al., 1996 · shape-controlled synthesis ↗Shape-dependent catalytic properties of Pt nanoparticles, 2010 ↗← Keep exploring